Characterizing Novel Methoxybenzene via Boron-ate Complex

Characterizing Novel Methoxybenzene via Boron-ate Complex Synthesis and Characterization of Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene via Boron-ate Complex Habib Hussain[*], Syeda Rubina Gilani, Zulfiqar Ali, Imdad Hussain, Hajira Rehman   Abstract: Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene was synthesized through boron-ate complex. 3-(4-methoxyphenyl)propyl diisopropylcarbamate was reacted with allylboronic acid pinacol ester in the presence of N,N,N,N-tetramethylethyllenediamine (TMEDA) to give secondary boronic ester which was further reacted with (vinylsulfonyl)benzene by using Grubbs Hoveyda II. Resulting product (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane was then treated with 1-bromo-3,5-bis(trifluoromethyl)benzene in the presence of n-BuLi to get nucleophilic boron-ate complex. (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene was obtained in excellent yields by stirring boron-ate complex at 50oC for 1h and refluxing for 15h. Keywords: Lithiation Borylation, Secondary Boronic Ester, Olefin Cross Metathesis, 1-bromo-3,5-bis(trifluoromethyl)benzene , Boron-ate Complex 1. Introduction Olefin metathesis chemistry1 has led a number of opportunities in organic synthesis. Olefin metathesis2involves the redistribution of fragments ofalkenes by regeneration of carbon-carbondouble bonds. There are numerous applications of olefin metathesis and it is an important methodology to produce reagents. Addition of aryl lithium reagents to secondary boronic esters results to a new class of chiral organometallic-type reagents which have broad utility in asymmetric organic synthesis. R. Larouche-Gauthier3 formed intermediate boron-ate complex by adding an aryllithium reagent to a secondary boronic ester. It behaved as a chiral nucleophile and maximum enantioselectivity was found by using electron withdrawing groups on aryllithium. Habib Hussain4 studied the effect of steric bulk of aryllithium on stereoselectivity of boron-ate complexes. Hoffmann5 obtained chiral Grignard reagents from sulfoxides Mg exchange reaction of halosulfoxides. Herbert C. Brown6 investigated iodination of the ate- complexes from various B-alkoxyborinane derivatives and 1-alkynyllithium. E. Vedejs7 synthesized ate- complexes which contained stereogenic boron by reacting trivalent boranes with nucleophiles. They noticed that stability of ate-complex depend upon the electronegativity of substituents attached to b oron. Ryschkewitsch, G. E8 resolved chiral boron-ate complexes by classical methods. Anna Bernardi 9 determined the role of ate-complxes im aldol stereoselectivity. In the recent paper, we reported the synthesis of Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7). It was characterized by IR, 1H, 13C and ms. Lithiation-Borylation was used to synthesize the secondary boronic ester and by using olefin cross metathesis, it gave (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane when reacted with (vinylsulfonyl)benzene. (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane was converted into ate-complex when on heating produced the desired product. 2. Experimental Section 2.1. Materials: n-butyllithium (nBuLi), sec. butyllithium solution (sBuLi) (1.6M), pinacol, N,N,N,N-tetramethylethyllenediamine (TMEDA), (vinylsulfonyl)benzene, Grubbs Hoveyda II and 1-bromo-3,5-bis(trifluoromethyl)benzene were purchased from Sigma Aldrich. All reagents were used as such as received. To avoid from moisture diethyl ether (Et2O) and tetrahydrofuran (THF) were dried with 4 A ° molecular sieves. The experiments were performed using schlenk line under nitrogen atmosphere in the absence of air and moisture. 2.2. Synthesis and Characterization of 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3): To a solution of 3-(4-methoxyphenyl)propyl diisopropylcarbamate (1.0g, 3.41mmol, 1.0eq) (1) and N,N,N,N-tetramethylethyllenediamine (TMEDA) (0.61mL, 4.09mmol, 1.2eq) (2a) in Et2O (17mL) at -78oC, Sec. BuLi (1.6M in 92:8 cyclohexane/hexane, 2.9mL, 3.75mmol, 1.1eq) was dropwise added and stirred for 5h at -78oC. Then allylboronic acid pinacol ester (0.77mL, 4.09mmol, 1.2eq) (2) was dropwise added to the reaction mixture and further stirred at -78oC for 1h and allowed to warm to room temperature. At this stage, a solution of MgBr2.OEt2 in Et2O, made as follows, was added to the reaction mixture. [At room temperature, 1,2-dibromoethane (0.60mL, 6.88mmol, 1.0eq) was added into a suspension of magnesium (0.17g, 6.88mmol, 1.0eq) in Et2O (8.6mL). The reaction flask was further stirred for 2h after placing into a water bath in order to control the moderate exotherm]. Biphasic mixture having two layers thus obtained was added to the former reaction mixture via syringe and then refluxed for 16h . After cooling the reaction mixture to room temperature it was quenched with water. Et2O was added, the layers were separated and the aqueous phase was extracted with Et2O. The combined organic layers were washed with 1N HCl, 1N NaOH, water and brine, dried (MgSO4), concentrated and purified by column chromatography (SiO2) and pure (R)-2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) (0.84g, 77.60%) was obtained as colorless oil. The reaction is given in Figure 1. 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.09 (2H, d, J=8.80 Hz, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.81 (2H, d, J=8.80 Hz, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 5.86 – 5.75 (1H, m, CH=CH2) 5.04 (1H, d, J=2.20 Hz, CH=CHH) 4.94 (1H, d, J=10.27 Hz, CH=CHH) 3.78 (3H, s, OCH3) 2.63 2.48 (2H, m, ArCH2CH2CHBCH2) 2.27 2.11 (2H, m, ArCH2CH2CHBCH2) 1.78 1.58 (2H, m, ArCH2CH2CHBCH2) 1.25 (12H, s, 4 à ¯Ã¢â‚¬Å¡Ã‚ ´ CH3) 1.08 1.18 (1H, m, ArCH2CH2CHBCH2) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.6 (1C, -OCH3), 138.4 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH), 135.0 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH), 129.2 (1C, ArC-O), 114.9 (1C, -CH2CH=CH2), 113.6 (1C, -CHb=CH2), 83.0 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ C(CH3)2), 55.2 (1C, ArCCH2), 35.3 (1C, CH2CH2CHB), 34.5 (1C, -CH2CHB), 33.1 (1C, -CHBCH2CH), 24.9 (1C, -CH2CH2CHB), 24.8 (4C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ (CH3)2C). 11B NMR (96.23 MHz, None) ÃŽ ´ ppm 33.24 IR (film): ÃŽ ½ (cm–1) 3026 (sp2C-H Stretch), 2977, 2924, 2852 (sp3 C-H Stretch), 1511, 1456(sp2 C=C Stretch), 1243, 1175, 1142 (sp3C-O Stretch), 846, 822, 670 (sp2 C-H oop bending). 2.3. Synthesis and Characterization of (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5): Grubbs-Hoveyda II (4a) (3.9mg, 0.0063mmol, 0.05eq) was added to a solution of 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) (40mg, 0.126 mmol, 1.0eq) and (vinylsulfonyl)benzene (4) (0.0635g, 0.378mmol, 3.0eq) in CH2Cl2 (2mL). After fitting a condenser to the flask, reaction mixture was refluxed for 15h under nitrogen. The reaction mixture was then reduced in volume to 0.5mL and purified directly on a silica gel column eluting with 9:1 Pet. Ether/ EtOAc to provide the desired product (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) as dark brown solid (0.0438g, 77.25%)10. m.p. 82.0oC 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.88-7.84 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.62-7.56 (1H, m, , 1 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.54-7.48 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 7.05-6.99 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.96 (1H, t, J=6.97 Hz, CH2-CH=CH) 6.84-6.77 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.31 (1H, dt, J=15.16, 1.47 Hz, CH2-CH=CH) 3.78 (3H, s, -CH3) 2.59-2.45 (2H, m, CH2-CH2-CHB) 2.43-2.26 (2H, m, CH2-CHB-CH2) 1.77-1.66 (1H, m, CH2-CHB-CHH) 1.63-1.53 (1H, m, CH2-CHB-CHH) 1.27-1.21 (1H, m, CH2-CHB-CH2) 1.18 (12 H, s, 4 à ¯Ã¢â‚¬Å¡Ã‚ ´ CH3) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.7 (1C, ArC-O) 146.9 (1C, ArC-S) 140.8 (1C, CH=CH-S) 134.2 (1C, CH=CH-S) 133.1 (1C, ArC-CH2) 130.6 (1C, ArCH) 129.2 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 129.1 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 127.5 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 113.7 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 83.4 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ C(CH3)2) 55.2 (1C, OCH3) 34.1 (1C, CH2CHBCH2) 33.1 (1C, CH2CH2CHB) 32.8 (4C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ (CH3)2C) 24.8 (1C, -CHBCH2CH) 24.7 (1C, CH2CH2CHB) 11B NMR (96.23 MHz, None) ÃŽ ´ ppm 33.24 IR (film): ÃŽ ½ (cm–1) 2977, 2924 (sp3 C-H Stretch), 1511, 1446(sp2 C=C Stretch), 1244, 1176, 1141 (sp3C-O Stretch), 822, 730, 687 (sp2 C-H oop bending). 2.4. Synthesis and Characterization of (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7): To a solution of 3,5-(CF3)2C6H3Br (24.6mg, 0.084mmol, 1.2eq) in THF (1.9mL) at -78oC was added n-BuLi (1.6M in hexanes, 0.053mL, 0.084mmol, 1.2eq) dropwise. The mixture was stirred for 1 hr at -78oC before a solution of boronic ester (32mg, 0.070mmol, 1.0eq) in THF (1.5mL) was added dropwise. The reaction mixture was stirred for 30min at -78oC and 30min at room temperature to form boron-ate complex which was further heated at 50oC for 1 hr and refluxed for 15hr. Reaction was quenched with water, EtOAc was added and layers were separated. The aqueous phase was extracted with EtOAc. Then layers were combined, washed with brine, dried (MgSO4), concentrated. The crude mixture was finally purified by column chromatography (SiO2, 2:1 Pet.Ether/EtOAc) to get desired product as colorless oil (19.87mg, 62.10%). 1H NMR (400 MHz, CDCl3) ÃŽ ´ ppm 7.14-7.07 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.85 6.80 (2H, m, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArH) 6.30 (1H, dt, J=17.00, 10.21 Hz, CH=CH-CH=CH2) 6.12-5.97 (1H, m, CH=CH-CH=CH2) 5.78-5.69 (1H, m, CH=CH-CH=CH2) 5.21-5.06 (1H, m, CH=CHH) 4.99-4.95 (1H, m, CH=CHH) 3.79 (3H, s, -CH3) 2.70-2.60 (2H, m, CH2CH2CH) 2.52-2.33 (2H, m, CH2CH2CH) 13C NMR (100 MHz, CDCl3) ÃŽ ´ ppm 157.7 (1C, ArC-O) 137.0 (1C, CH=CH2) 133.7 (1C, CH=CH-CH=CH2) 132.0 (1C, ArC-CH2) 129.5 (1C, CH=CH-CH=CH2) 129.1 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 114.9 (1C, CH=CH2) 113.6 (2C, 2 à ¯Ã¢â‚¬Å¡Ã‚ ´ ArCH) 55.1 (1C, CH3) 34.6 (1C, CH2CH2CH) 34.5 (1C, CH2CH2CH) IR (film): ÃŽ ½ (cm–1) 2955, 2921, 2852 (sp3 C-H Stretch), 1737, 1461(sp2 C=C Stretch), 1277, 1184, 1137 (sp3C-O Stretch), 967, 805 (sp2 C-H oop bending). HRMS (ESI) calcd. for C13H17O [M+H]+ 189.1279, found 189.1287. 2.5. Equipments 1H and 13C spectral measurements were done by using Varian NMR (400 MHz) spectrometer (model DMX 400). For protons, the chemical shifts were measured relative to tetramethylsilane (TMS) at d = 0 ppm. 3. Results and Discussion Starting material 2-(1-(4-methoxyphenyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (3) has been synthesized as colorless oil in excellent yields (77.6%) (table 1, entry 1) by using Lithiation-Borylation methodology; Carbamate (1) was reacted with pinacol (2) by using TMEDA (2a) at suitable conditions (fig.1). Spectral studies proved the structure as mentioned in literature11. By using application of olefin cross metathesis, boronic ester (3) was then reacted with (vinylsulfonyl)benzene (4) to give (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) as dark brown solid. Yield was again excellent (table 1, entry 2) for this reaction. Table 1: Physical states and yields Entry Substances Physical States Melting points Yield (%) 1 Colorless oil 77.60 2 Dark brown solid 82.0oC 77.25 3 Colorless oil 62.10 Boron-ate complex (6) which acted as nucleophile was synthesized by reacting (E)-2-(1-(4-methoxyphenyl)-6-(phenylsulfonyl)hex-5-en-3-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (5) with aryllithium (5a). Boron-ate complex (6) showed best nucleophilic character by using 3,5-(CF3)2C6H3Br (5a) as aryllithium11 and it was then stirred at 50oC for 1hr and then refluxed for 15hrs and desired product (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene (7) was collected. 4. Conclusions: Novel (E)-1-(hexa-3,5-dien-1-yl)-4-methoxybenzene has been synthesized through a novel route and characterized by spectral techniques like IR, 1H, 13C and ms. Boron-ate complex was successfully converted into aromatic dienes. This novel synthetic route resulted in excellent yields. Acknowledgment: Authors gratefully acknowledge financial support to the work by Higher Education Commission of Pakistan and moreover authors acknowledge the Department of Chemistry, University of Engineering and Technology, Lahore-Pakistan and Superior University Lahore-Pakistan for guidance, research and laboratory facilities. References: Grubbs, R. H.; Chang, S. Tetrahedron 1998, 54, 4413–4450 Astruc D. New J. Chem., 2005, 29, 42-56. R. Larouche-Gauthier, T.G. Elford and V.K. Aggarwal, J. Am. Chem.Soc., 2011,133, 16794. Habib Hussain, Syeda Rubina Gilani, Zulfiqar Ali and Imdad Hussain, Asian Journal of Chemistry; 2013, 25, 17, 9965-9969 Hoffmann, R. W. Chem. Soc. Rev. 2003, 32, 225. Herbert C. Brown, D. Basavaiah, and N. G. Bhat, D. Basavaiah, and N. G. Bhat, J. Org. Chem. 1986, 51, 4518-4521 E. Vedejs, S. C. Fields, S. Lin, and M. R. Schrimpf, J. Org. Chem. 1995, 60, 3028-3034. Ryschkewitsch, G. E.; Garrett, J. M. J. Am. Chem. Soc. 1968, 90, 7234. Anna Bernardi, Angiolina Comotti, Cesare Gennari, Cheryl T. Hewkin, Jonathan M. Goodman, Achim Schlapbach and Ian Paterson, Tetrahedron 50, 4, 1227-1242, 1994. Bruce H. Lipshutz, Subir Ghorai, Zarko V. Boskovic, Tetrahedron, 64, 29, 2008, 6949-6954. Habib Hussain, Syeda Rubina Gilani, Zulfiqar Ali and Imdad Hussain, Asian Journal of Chemistry, In Press. [*]Corresponding Author: Habib Hussain

Development of Location Detection System Using Passive Sonar Frequency

Development of Location Detection System Using Passive Sonar Frequency Chapter I. The Problem and Its BackgroundIntroductionHuman echo sounding is an ability of worlds to observe objects in their environment by feeling reverberations from those objects. By actively making sounds people trained to point themselves with echo sounding can construe the sound moving ridges reflected by nearby objects and be able to accurately placing their location.Background of the StudyInvention is the key to a productive and comfortable hereafter, the more advanced our lives turn in to the more convenience we receive, doing arduous undertaking be done with easiness and puting our human restrictions to greater highs, but no affair how far we go on this pursuit of doing our lives more convenient clip is ne'er in our side and devolution comes along with it. Disabilities are hinderances that would halt one’s life to be enjoyed to the fullest, people would necessitate to take therapies and tonss of clip merely to get by up with what was lost from them, with the usage of invention we could do systems that would help others and be able to get by up and unrecorded normal lives even with such dysfunctional variety meats or amputations. Blindness is a really common disablement among the peoples throughout the word. Harmonizing to the World Health Organization ( WHO ) 285 million people are visually impaired worldwide, 39 million are unsighted and 246 have low vision. About 90 % of the world’s visually impaired live in developing states. A individual who can non see at 6 metre nor has a field vision of 10or less is considered lawfully blind. 95 % of people classed as lawfully blind have some vision. To be classed as blind, there is a entire loss of vision. They need help to walk and all other day-to-day indispensable plants. So we the advocates show a system that tries to take the expletive of sightlessness and do them self-dependent to make their day-to-day jobs. It is a coaction of multiple devices that cooperate with one another to supply navigational counsel by using the echo sounding and echo sounder. The system consists of multiple transceivers that are programmed with the usage of programmable circuits to give out specified orders or bids that seasonably calculates the distance from one another to supply accurate readings of the location of objects and specific countries.Aims of the StudyThe general aim of this survey is to develop a location sensing system that utilizes echo sounders like functionality. In line with this, the undertaking aims to accomplish the following specific aims:To develop a navigational system that would supply assistance to the visually impaired or the blind.To build a system by using multiple transceivers that cooperate with one another and be able to pass on with the user via earphone and give accurate and effectual orders.To place the restriction of the system and what would function as a correctional response to the said jobs or any possible class of action.Significance of the StudySignificance of the survey is to supply assistance to handicapped people for them to populate normal unrecorded and be able to get by up from their loss and would non take tonss of clip merely to cover with. The following groups of people and organisations that will profit from the survey are:For the Blind – The system would give assistance to the people that are blind for it provides pilotage with the usage of sound moving ridges that would move as their eyes and give counsel by the agencies of giving the location and possible obstructors that they may meet.For the Visually Impaired – The undertaking shed light to a possibility that they should non fear sightlessness ( if their damage unluckily leads to blindness ) and would still be able to populate normal lives with the aid of the system.For the Students – Our Undertaking proposal will function as mention and usher for the pupils to develop, innovate, better or make great and working thesis. This can give them proficient information largely in these present tendencies where huge engineerings upgraded.For Future Researchers – Our proposed undertaking will assist them to give an thought about what they will g estate and better about this survey.Scope and RestrictionThe usage of â€Å"The survey will concentrate on supplying navigational assistance to the blind† , â€Å"It includes the survey about things that affect the sound wave that travels† , â€Å"The survey consists of multiple transceivers that cooperate with one another that makes a web or system† , and â€Å"The coverage of the survey entirely focuses on supplying assistance to the visually impaired by using echo sounder like functionality of the system† could assist show the range while the usage of â€Å"This survey is limited to people that are sing ocular loss†¦Ã¢â‚¬  , â€Å"The survey does non cover elaborate information about the constituents but merely sufficient information to warrant its functionality† , and â€Å"It does non seek to include the application of the system in out-of-doorss plus the possible effects of certain appendages that could impact the system† could assist show the restrictions.Conceptual ModelIn order to successfully accomplish the coveted result of this survey, certain processs, demands and thoughts were carefully discussed to gestate the project’s design and development. After a long deliberation and brainstorming, one idea was agreed upon in which resulted into one construct. Fig. 1 Conceptual model of the survey Fig. 1 shows the conceptual model of the survey. It covers the three major parts: the input that uses transceivers to bring forth and have sound that travel trough air and bouncinesss off solid objects, the procedure that utilizes multiple transceivers that communicate with the nomadic transceiver by directing answers that would be processed by the transcriber and so delivered to the user by the agencies of the earphone, and the end product phases that provide the user existent clip calculation and update to the distance and whereabouts of the stationary transceiver and possible obstructors.Operational Definition of FootingsHuman echo soundingIs an ability of worlds to observe objects in their environment by feeling reverberations from those objects.SonarSoundNitrogenavigationAneodymiumRoentgenanging is a technique that usessoundpropagation tonavigate, communicate with or detect objects on or under the surface of the H2O, such as other vass.DegenerationDeterioration and loss of map i n the cells of a tissue or organ

The One System to Use for College Term Papers Writing Uncovered

The One System to Use for College Term Papers Writing Uncovered Understanding College Term Papers Writing The cost of an essay depends upon the quantity of effort the writer has to exert. Selecting the topic you are especially interested in will make it simpler that you write the expression paper with fantastic zeal and enthusiasm. Don't hesitate in asking for help, it not only enrich your understanding of the topic, but in addition assist you in getting good grades. A student should take their time, persistence and diligence as a way to compose an excellent college term paper. Make sure it's original and logical. Students might need to compose reports for any subject they're taking in school. It's not strange for students at college level to truly feel overwhelmed by the range of. The Birth of College Term Papers Writing If you wish to emerge the very best in your class all the moment, then buying online papers are sometimes an excellent resolution for you. 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Skinners Theories of Behaviorism Essay - 912 Words

Behaviorism is by far one of the most interesting fields of psychology in my opinion. B.F. Skinner’s view on behaviorism was that a person’s actions are controlled by rewards and punishments. Relating this to a real life situation, a great example of this would be a parent and a child. Behavioral analysis is how a person’s behaviours are based on the individuals’ personal history and past experiences. This is different then radical behaviorism, which Skinner fell into. Skinner believed that mental events, such as thinking, were not needed to explain behavior. A parent raising a child deals with a lot of operant conditioning if they know it or not. A parent is always trying to teach a child right and wrong. From operant conditioning†¦show more content†¦The changing of the channel is removing the unwanted television program. Punishment refers to a response with an unpleasant consequence. Punishment unlike reinforcement decreases the likelihood tha t the response will occur again. Positive punishment is any stimulus that, when added to a situation decreases the probability that a given behavior will occur. If a child is destroying the house by painting the walls and the parent catches them doing this act. The parent may spank the child adding an unpleasant consequence and hoping this behavior will not occur again. Negative punishment is any stimulus that, when removed from the situation decreases the probability that the behavior will occur again. A lot of times the negative punishment is called the response cost. If a child is hitting their sister instead of adding an action such as hitting the child a parent (mostly permissive parenting) will remove this action. Another way this can be seen is if you take away the child’s playtime and replace it with a timeout. The child is having a pleasant event removed, which will decrease the chance that the child will hit their sibling again. All of these reinforcements and punis hments are shaping the child to grow into an individual who has the right morals in life. If a parent wants their child to do well in school and clean the house they need to set a series of gradual daily goals for their child. The parent then can reward them forShow MoreRelated B. F. Skinner Essay1590 Words   |  7 Pageswas a very straightforward man and a very educated man. His theories have helped mankind in many ways. He has studied the behavior patterns of many living organisms. Skinner was a well-published writer. His work has been published in many journals. He also has written many books on behaviorism. His most important work was the study of behaviorism.   Ã‚     Ã‚  Ã‚  First began by John B. Watson, behaviorism is one of the most widely studied theories today. B.F. Skinner and His Influence in Psychology B.F. SkinnerRead MoreThe Ambiguity Of Behaviorism : Human Equality And Freedom Essay1286 Words   |  6 Pages The Ambiguity of Behaviorism: Human Equality and Freedom YI TSAM MARY KONG University of British Columbia The Ambiguity of Behaviorism: Human Equality and Freedom Behaviorism on learning and memory occupies an important position in the history of psychology. John B. Watson is the father of behaviorism while B.F. Skinner is the most famous behaviorist of the twentieth century. Watson’s methodological behaviorism means that it is only the behaviors of an individual thatRead MoreVerbal Behavior and Verbal Response1328 Words   |  5 PagesSkinner, in ‘A review of B. F. Skinner’s verbal Behavior’ and ‘Selections from Science and Human Behavior’, discusses the idea of operant conditioning in human behavior, and functional analysis in human verbal behavior respectively. Both ideas seek to explain human behavior, whether in physical action or in verbal communication. 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Watson helped with defining the study of behavior anticipated Skinners emphasis on operant conditioning and the importance of learning and environmental influencesRead MoreThe Theory Of Operant Conditioning Theory Essay746 Words   |  3 Pagesas operant conditioning (Rholetter, 2013). Operant conditioning is one of two theories in learning that illustrates behaviorism (Kretchmar, 2015). It is according to Rholetter (2013), â€Å"the idea that behavior is the learned result of consequences†. Skinner believed that learning during operant conditioning is done based upon the outcome of a given situation (Lefrancois, 2012, p. 91). His operant conditioning theory is constructed on reinforcements consisting of positive, negative, primary andRead MoreComparison of Maslow’s Hierarchy of Needs with Skinners Behaviorist Theory1587 Words   |  7 PagesComparison of Maslow’s Hierarchy of Needs with Skinners Behaviorist Theory Typing Template for APA Papers: A Sample of Proper APA Fifth Edition Formatting Deborah DiBerardino Grand Canyon University: Educational Psychology EDU 313N Amy Wilkinson August 5, 2012 Comparison of Maslow’s Hierarchy of Needs with Skinners Behaviorist Theory The definition of motivation according to Dictionary.com is: â€Å"The reason or reasons one has for acting or behaving in a particular way; theRead More B. F. Skinner Essay1073 Words   |  5 Pagesmother, Grace M. Burrhus, was a stenographer and a secretary, in a law office and later in a railroad chief executives office. His father, William A. Skinner, was an attorney, who studied law with another local attorney at a New York Law School. Skinners parents were both good students. His father had bought several sets of books, so there was a lot of reading material their children. Skinner said that his parents never used physical punishment, except for the time they washed his mouth out withRead MoreBehavioral Psychology and BF Skinner916 Words   |  4 Pagesfor his theories in behaviorism and remains as one of the best and most controversial figures in the world of psychology. Most of his work throughout his lifetime dealt with both positive and negative reinforcements and the after-effects it had on behavior. B.F. Skinner understood that as humans, everything that we do or become is through the methods of rewards and punishments. Though his time has long since passed, his ideology and his written works such as Walden II and About Behaviorism have applied